Ruby

In affiliation with GemologyOnline.com
From The Gemology Project
Ruby
Chemical composition Al2O3
Crystal system Trigonal
Habit Prismatic, tabular
Cleavage None, twinned stones may show parting
Fracture Conchoidal
Hardness 9
Optic nature Uniaxial -
Refractive index 1.762-1.770
(+.009,-.005)
Birefringence 0.008-0.010
Dispersion Low, 0.018
Specific gravity 4
Lustre Vitreous to subadamantine
Pleochroism Strong; puplish-red to orangy-red
3.30 ct heated Mong Hsu ruby
Photo by Jeff Scovil
Courtesy of R.W. Wise Goldsmiths

Ruby is the red variety of the mineral corundum. When corundum occurs in any other color it is referred to as a sapphire. Rubies are mined primarily in Burma, Sri Lanka, Thailand, Cambodia, Vietnam, Kenya, Tanzania, Mozambique, Madagascar, India, Afghanistan and Tajikistan. More important than the gem's locality of origin is the actual color and clarity of the stone. Rubies that are the most valuable will be pure red in color, without any modifying tones of violet, orange or brown and are transparent in clarity. A fine ruby is among the most expensive of any stone in the world.

The brilliant red color of the ruby has given birth to a number of myths and legends. One is that rubies store vast quantities of heat and when placed in water, they will cause the water to boil. Obviously this is an exaggeration, but some swear if you hold a ruby in your left hand, you'll feel bursts of heat. Ruby, none the less, is a powerful stone and has long been considered a magnet for prosperity, attracting abundance both materially and spiritually.

The word ruby is derived from the Latin rubeus, meaning "red".

Contents

Diagnostics

Spectrum

Spectrum of ruby: both natural and synthetic.

UV Fluorescence

The chromium present in ruby causes a natural red fluorescence which is stimulated by both visible and invisible (ultraviolet) light. However, when a ruby contains a significant amount of iron in addition to the chromium, the fluorescence is reduced. Rubies naturally fluoresce stronger to long wave UV than short wave. Stones with the strongest fluorescence are often a pinkish red color in daylight.

Phenomena

  • Asterism: 6-rayed stars are common in ruby; rarely, 12-rayed stars have been found.
  • Chatoyancy: Although cat's eye rubies have been reported, true cat's eye rubies (where silk forms in a single direction) have not been found.
  • Trapiche: Rubies that display a fixed six-spoke pattern of inclusions similar to trapiche emeralds have been found in Mong Hsu, Burma.

Occurrence

The most famous source of fine rubies is Upper Burma, now known as Myanmar. The ruby mines of Myanmar are older than recorded history; Stone Age and Bronze Age mining tools have been found in the mining area of Mogok. Rubies from the legendary mines in Mogok often have a pure red color, which has been described as "pigeon's-blood" although that term is more fanciful than an actual practical standard in the trade today. Myanmar also produces intense pinkish red rubies which are almost electric in color. Many of the rubies from Burma have a strong fluorescence when exposed to ultraviolet rays like those in sunlight. Fine rubies are also found in Myanmar at Mong ('Maing') Hsu and at Nanyazeik (Namya).

Much lesser known are deposits of ruby found in Afghanistan. Although reports of rubies mined in Afghanistan were first chronicled by Marco Polo, the mines have long been shrouded in secrecy and mystery. The mines he referred to are for "balas rubies" (spinels). The actual locality is at Kuh-i-Lal in present-day Tajikistan, just opposite the Afghan border. True ruby is also mined in eastern Tajikistan at Snijnie (aka Snagnyi or Snezhnoye).

Ruby from Afghanistan

The crystal on the left, is semi-translucent and heavily included. It can be described as a subhedral ruby crystal nestled in a matrix of white calcite/dolomite marble, dotted with pseudo-hexagonal books of muscovite. It is very strongly fluorescent displaying bright red with LWUV, and weaker red with SWUV.

True rubies are found in Afghanistan at Jegdalek, east of Kabul, which is located in a continental collision zone between the Asian and Indian plates. The deposits occur in metamorphosed limestone (marble) which are found on both plates.

Next to Myanmar, the most important historic source of ruby is Sri Lanka. In modern times, fine rubies have been found along the Thai/Cambodian border between Chanthaburi (Thailand) and Pailin (Cambodia). These deposits were the most important in the world between about 1965 and 1995. Today they are exhausted.

An additional source of ruby is Vietnam. Fine stones have been found at both Quy Chau (along the Lao border) and Yen Bai, north of Hanoi.

East Africa has been a major source of ruby since the 1960's, with a number of sources existing in Kenya, Tanzania and Mozambique. In addition, Madagascar has a number of ruby deposits of varying importance.


Synthesizing Methods

  • Flame fusion (aka Verneuil): This is the most common synthetic ruby.
  • Flux melt (Chatham, Kashan, Ramaura, Knischka, Russia)
Flux grown synthetic Ramaura ruby, displaying hexagonal patterns and flux relics.
Photo courtesy of Alberto Scarani


  • Czochralski (pulling)
  • Floating zone (Seiko)

Inclusion images

Apatite in untreated Mogok ruby
Photo courtesy of Apsara.co.uk
Apatite in untreated Mogok ruby
Photo courtesy of Apsara.co.uk
Distorted calcite guest crystals in untreated Mogok ruby
Photo courtesy of Apsara.co.uk

Rutile silk in untreated Mogok ruby
Photo courtesy of Apsara.co.uk


Heat treated Mong Hsu ruby
Photo courtesy of Apsara.co.uk
Partially dissolved rutile silk in heat treated Vietnamese ruby
Photo courtesy of Apsara.co.uk

Rounded calcite guest crystals with 'treacle' colour swirls in un-heated Mogok ruby
Photo courtesy of Apsara.co.uk
Growth lines, guest crystals and un-disolved rutile silk in un-heated Mogok ruby
Photo courtesy of Apsara.co.uk


Treacle colour swirls, growth lines and guest crystals in un-heated Mogok ruby
Photo courtesy of Apsara.co.uk
Rounded calcite guest crystals in un-heated Mogok ruby
Photo courtesy of Apsara.co.uk
Unusual acicular guest crystal and small particle inclusions in un-heated Mogok ruby
Photo courtesy of Apsara.co.uk
Distorted calcite guest crystal in un-heated Mogok ruby
Photo courtesy of Apsara.co.uk


Guest crystals in un-heated Mogok ruby
Photo courtesy of Apsara.co.uk
Apatite and calcite guest crystals reflecting within an un-heated Mogok ruby
Photo courtesy of Apsara.co.uk


Enhancements

Common enhancements to rubies include:

  • Heat treatment: This is one of the earliest ruby treatments, and has been performed for over 1000 years. Heating at about 800–1200°C in an oxidizing atmosphere removes the blue tint from ruby, making the stones appear more red. Higher temperature heating (1400–1800°C) can also improve clarity by dissolving rutile silk. Heating in the presence of a flux can artificially heal fissures with tiny quantities of synthetic corundum.
  • Bulk ('lattice') diffusion: The diffusion of coloring agents (chromium, in the case of ruby) into the stone via high-temperature heating. Diffusion rates for chromium are very slow; thus only a surface layer of color is found. The same process can diffuse titanium into the stone, producing an artificial asterism.
  • Fracture filling: Oil, wax or plastic (with or without dye)
  • Lead glass filling: Hides fissures, improves color and increases weight
Natural ruby, displaying a surfacing area of glass filling with bubbles
Photo courtesy of Alberto Scarani
Blue flashes in a glass filled ruby, diagnostic for lead-glass filing.
© Tim Spauwen

GIA's Video on Lead Glass Filled Ruby

Sources

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